Pd-catalyzed desulfitative and denitrogenative Suzuki-type reaction of arylsulfonyl hydrazides

Zhong Shuangling; Sun Chenggang; Dou Sen; Liu Wencong

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Pd-catalyzed desulfitative and denitrogenative Suzuki-type reaction of arylsulfonyl hydrazides

机译：芳基磺基肼的PD催化脱硫和脱氮铃木型反应

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A palladium-catalyzed desulfitative-denitrogenative coupling of arylsulfonyl hydrazides and arylboronic acids with the assistance of catalytic ligands is described. The reaction showed very good selectivity and tolerated a wide range of functionalities without the aid of expensive copper-or silver-based stoichiometric co-oxidants. We have successfully applied this new cross-coupling reaction to the synthesis of terphenyls and OTBN.

机译：描述了芳基磺酰肼和芳基硼酸与催化配体的辅助脱硫脱氮偶联偶氮偶联的脱硫偶联偶联。该反应显示出非常好的选择性，并且耐受诸多功能，而不借助于昂贵的铜或银基化学计量共氧化剂。我们已成功地将这种新的交叉偶联反应应用于三苯基和OTBN的合成。

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《RSC Advances》 |2015年第34期|共5页
作者
Zhong Shuangling; Sun Chenggang; Dou Sen; Liu Wencong;
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作者单位

Jilin Agr Univ Coll Resources &

Environm Changchun 130118 Peoples R China;

Jilin Agr Univ Coll Resources &

Environm Changchun 130118 Peoples R China;

Jilin Agr Univ Coll Resources &

Environm Changchun 130118 Peoples R China;

Jilin Agr Univ Coll Resources &

Environm Changchun 130118 Peoples R China;

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正文语种 eng
中图分类化学;
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1. Pd-catalyzed desulfitative and denitrogenative Suzuki-type reaction of arylsulfonyl hydrazides [J] . Zhong Shuangling, Sun Chenggang, Dou Sen, RSC Advances . 2015,第34期

机译：芳基磺基肼的PD催化脱硫和脱氮铃木型反应
2. Desulfinative and denitrogenative palladium-catalyzed cross-coupling of arylsulfonyl hydrazides with aryl diazonium salts [J] . Shang Yonghui Applied Organometallic Chemistry . 2018,第11期

机译：用芳基重氮盐的芳基磺酰肼的脱硫和脱氮钯催化的交联偶联
3. Palladium-Catalyzed Desulfitative Cross-Coupling of Arylsulfonyl Hydrazides with Terminal Alkynes: A General Approach toward Functionalized Internal Alkynes [J] . Qian Liang-Wei, Sun Mengli, Dong Jianyu, The Journal of Organic Chemistry . 2017,第13期

机译：钯催化芳基磺酰基含芳基磺酰肼的脱硫交叉偶联与炔醇末端：官能化内部alkynes的一般方法
4. Catalytic Reactions of Ionic Liquids as Substrates: Pd-Catalyzed Coupling Reaction of Imidazolium-Based Ionic Liquids with Aryl Halides [C] . Takahide Fukuyama, Taifur Rahman, Hideo Takahashi Symposium on Organometallic Chemistry . 2007

机译：离子液体作为底物的催化反应：咪唑鎓基离子液体与芳基卤化物的PD催化偶联反应
5. Development and Application of Chiral Biphenol-based Diphosphinite Ligands to Pd-Catalyzed Asymmetric Allylic Substitution Reactions. [D] . Zang, Yang. 2014

机译：手性双酚基二亚膦酸酯配体在钯催化的不对称烯丙基取代反应中的开发与应用。
6. Synthesis of Cyclic Guanidines Bearing N-Arylsulfonyl and N-Cyano Protecting Groups via Pd-Catalyzed Alkene Carboamination Reactions [O] . Luke J. Peterson, Jingyi Luo, John P. Wolfe -1

机译：通过Pd催化的烯烃碳氨基化反应合成带有N-芳基磺酰基和N-氰基保护基的环状胍
7. Open-air oxidative mizoroki-heck reaction of arylsulfonyl hydrazides with alkenes [O] . Yuen, OY, So, CM, Kwong, FY 2016

机译：芳基磺酰肼与烯烃的露天氧化重氮-赫克反应

Pd-catalyzed desulfitative and denitrogenative Suzuki-type reaction of arylsulfonyl hydrazides

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