Construction of benzo[a]carbazole derivatives via Diels-Alder reaction of arynes with vinylindoles

Wu Lijun; Huang Hui; Dang Pan; Liang Yun; Pi Shaofeng

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Construction of benzo[a]carbazole derivatives via Diels-Alder reaction of arynes with vinylindoles

机译：苯并[a]咔唑衍生物的构建通过叶绿酱与乙烯基吲哚的alys- ald反应

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A new protocol for a highly efficienct and versatile Diels-Alder reaction of vinylindoles with arynes (generated form 2-(trimethylsilyl)aryl triflate) has been developed. Various functionalized benzo[a]carbazoles were afforded in good to perfect yields via [4 + 2] cycloaddition/aromatization.

机译：已经开发了一种新的乙烯基吲哚与ryγ的高效率和多功能Diels- ald反应的新方案（产生的2-（三甲基甲硅烷基）芳基三氟酯）。各种官能化苯并[a]咔唑良好地通过[4 + 2]环加成/芳香化完美收益。

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来源
《RSC Advances》 |2015年第79期|共4页
作者
Wu Lijun; Huang Hui; Dang Pan; Liang Yun; Pi Shaofeng;
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作者单位

Hunan Normal Univ Key Lab Assembly &

Applicat Organ Funct Mol Minist Educ Key Lab Chem Biol &

Tradit Chinese Med Res Changsha 410081 Hunan Peoples R China;

Hunan Normal Univ Key Lab Assembly &

Applicat Organ Funct Mol Minist Educ Key Lab Chem Biol &

Tradit Chinese Med Res Changsha 410081 Hunan Peoples R China;

Hunan Normal Univ Key Lab Assembly &

Applicat Organ Funct Mol Minist Educ Key Lab Chem Biol &

Tradit Chinese Med Res Changsha 410081 Hunan Peoples R China;

Hunan Normal Univ Key Lab Assembly &

Applicat Organ Funct Mol Minist Educ Key Lab Chem Biol &

Tradit Chinese Med Res Changsha 410081 Hunan Peoples R China;

Cent South Univ Forestry &

Technol Inst Appl Chem Changsha 410004 Hunan Peoples R China;

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正文语种 eng
中图分类化学;
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1. Construction of benzo[a]carbazole derivatives via Diels-Alder reaction of arynes with vinylindoles [J] . Wu Lijun, Huang Hui, Dang Pan, RSC Advances . 2015,第79期

机译：苯并[a]咔唑衍生物的构建通过叶绿酱与乙烯基吲哚的alys- ald反应
2. Direct Assembly of Benzo[a] carbazole-5-carboxylates via a Diels-Alder Reaction with Arynes and 3-Alkenylindoles [J] . Tao Yuan, Zhang Fei, Tang Chen-Yu, Asian Journal of Organic Chemistry . 2014,第12期

机译：通过芳烃和3-烯基吲哚的Diels-Alder反应直接组装苯并[a]咔唑-5-羧酸酯
3. Intramolecular Diels-Alder Reactions of 4H-Furo[3,4-b]indoles. New Syntheses of Benzo[a]carbazoles and Benzo[c]carbazoles [J] . Gordon W. Gribble, Richard A. Silva, Mark G. Saulnier Synthetic Communications . 1999,第4期

机译：4H-呋喃并[3,4-b]吲哚的分子内Diels-Alder反应。苯并[a]咔唑和苯并[c]咔唑的新合成
4. Tandem Diels-Alder Reactions of Arynes: New Method for the Synthesis of Large Poly cyclic Aromatic Compounds and Nanographenes [C] . Diego Pena, Alejandro Criado, Dolores Perez European Symposium on Organic Chemistry . 2009

机译：Arynes的串联Diels-Alder反应：用于合成大聚环芳族化合物和纳米的新方法
5. Enantioselective synthesis of substituted polycyclic heterocycles by rhodium-catalyzed ring-opening reactions of aryne Diels-Alder adducts [D] . Nguyen, Duc Trung. 2009

机译：芳烃Diels-Alder加合物的铑催化开环反应对映选择性合成多环杂环
6. Regioselective Diels-Alder cycloadditions and other reactions of 45- 56- and 67-indole arynes [O] . Neil Brown, Diheng Luo, David VanderVelde, -1

机译：区域选择性Diels-Alder环加成反应和45-56-和67-吲哚芳烃的其他反应
7. Asymmetric Diels-Alder Reaction of 2-Arylidene-1,3-indanediones with 2-Vinylindoles Catalyzed by a Sc(OTf)3/Bis(oxazoline) Complex：Enantioselective Synthesis of Tetrahydrocarbazole Spiro Indanedione Derivatives [O] . Fen Tan, Jiarong Chen, Ping Wang, 2014

机译：2-亚亚亚亚亚芳基-1,3-吲哚的不对称Diels-ald反应用Sc（OTF）3 /双（恶唑啉）复合物催化的2-乙烯基吲哚（Soxazoline）复合物：对四氢咔唑螺丝氨酸吲哚胺衍生物的对映选择性合成

Construction of benzo[a]carbazole derivatives via Diels-Alder reaction of arynes with vinylindoles

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