Recent advances in the application of Diels-Alder reactions involving o-quinodimethanes, aza-o-quinone methides and o-quinone methides in natural product total synthesis

Yang Baochao; Gao Shuanhu

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Recent advances in the application of Diels-Alder reactions involving o-quinodimethanes, aza-o-quinone methides and o-quinone methides in natural product total synthesis

机译：在天然产物总合成中涉及o-喹甲甲烷，AZA-O-醌甲烷和O-醌甲基化物的Diels-alder反应的应用近期进展

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In recent decades, transient and highly reactive ortho-quinodimethanes (o-QDMs), ortho-quinone methides (o-QMs) and aza-ortho-quinone methides (aza-o-QMs) have attracted much attention and have been extensively studied and applied in organic synthesis, especially natural product total synthesis. This review summarizes recent advances in Diels-Alder reactions involving in situ-generated o-QDMs, o-QMs and aza-o-QMs, highlighting the power and potential of this strategy in organic synthesis and natural product total synthesis. An overview of the methods for generating these intermediates is also available.

机译：近几十年来，瞬时和高反应性的喹硫代 - 喹喔烷（O-QDMS），Ortho-quinone Methares（O-QMS）和Aza-Ortho-quinone Methares（AZA-O-QMS）引起了很多关注并且已被广泛研究和适用于有机合成，尤其是天然产物总合成。本综述总结了涉及原位产生的O-QDMS，O-QMS和AZA-O-QM的DIELS-ALDER反应的最新进展，突出了该策略在有机合成和天然产物总合成中的功率和潜力。还提供了生成这些中间体的方法的概述。

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《Chemical Society Reviews》 |2018年第21期|共28页
作者
Yang Baochao; Gao Shuanhu;
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East China Normal Univ Shanghai Key Lab Green Chem &

Chem Proc Sch Chem &

Mol Engn 3663N Zhongshan Rd Shanghai 200062 Peoples R China;

East China Normal Univ Shanghai Key Lab Green Chem &

Chem Proc Sch Chem &

Mol Engn 3663N Zhongshan Rd Shanghai 200062 Peoples R China;

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正文语种 eng
中图分类化学;
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1. Recent advances in the application of Diels-Alder reactions involving o-quinodimethanes, aza-o-quinone methides and o-quinone methides in natural product total synthesis [J] . Yang Baochao, Gao Shuanhu Chemical Society Reviews . 2018,第21期

机译：在天然产物总合成中涉及o-喹甲甲烷，AZA-O-醌甲烷和O-醌甲基化物的Diels-alder反应的应用近期进展
2. Recent applications of intramolecular Diels-Alder reaction in total synthesis of natural products [J] . Heravi Majid M., Vavsari Vaezeh Fathi RSC Advances . 2015,第63期

机译：近期分子内二氧化铝反应在天然产物合成中的应用
3. Recent advances in the applications of Wittig reaction in the total synthesis of natural products containing lactone, pyrone, and lactam as a scaffold [J] . Heravi Majid M., Ghanbarian Manizheh, Zadsirjan Vahideh, Monatshefte fur Chemie . 2019,第8期

机译：Wittig反应在含有内酯，吡喃物和内酰胺作为支架的天然产物总合成中的恒定反应应用的最新进展
4. Hypoiodite-catalyzed Chemoselective Generation of Quinone Methides and Application to Tandem Reactions [C] . Kohei Nishioka, Muhammet Uyanik, Kazuaki Ishihara 日本化学会春季年会講演予稿集 . 2018

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5. Applications of samarium(II) iodide-promoted 8-membered ring cyclization reactions in natural product total synthesis: I. The total synthesis of (+)-isoschizandrin. II. Progress toward the total synthesis of variecolin. [D] . George, Kelly M. 2005

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6. Studies toward the Total Synthesis of ParvifolalsA/B: An Intramolecular o-Quinone Methide 4 + 2-Cycloaddition To Constructthe Central Tetracyclic Core [O] . DineshJ. Paymode, Chepuri V. Ramana, * 2019

机译：小分子酚的全合成研究A / B：构筑的分子内邻醌甲基4 + 2-环加成中央四环核
7. Application of the Diels-Alder reaction towards the total synthesis of embellistatin and natural product Inspired libraries [O] . Nash Justin Chemistry Faculty of Science UNSW 2013

机译：Diels-Alder反应在Embellistatin和天然产物的全合成中的应用

Recent advances in the application of Diels-Alder reactions involving o-quinodimethanes, aza-o-quinone methides and o-quinone methides in natural product total synthesis

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