Synthesis of ethyl (2E,5S)-7-{[tert-butyl(dimethyl)silyloxy]-methyl}-5-methylocta-2,7-dienoate, a universal C-7-C-14 building block for the preparation of amphidinolides B, D, G, H, and L

Mineeva I. V.

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Synthesis of ethyl (2E,5S)-7-{[tert-butyl(dimethyl)silyloxy]-methyl}-5-methylocta-2,7-dienoate, a universal C-7-C-14 building block for the preparation of amphidinolides B, D, G, H, and L

机译：乙基（2E，5S）-7-{[叔丁基（二甲基）甲硅烷基氧基]-甲基} -5-甲基辛基-2,7-二烯酸酯的合成，这是一种通用的C-7-C-14制备方法两性霉素B，D，G，H和L

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A new simple and efficient procedure has been developed for the asymmetric synthesis of the C-7-C-14 building block for cytotoxic macrolactones, amphidinolides B, D, G, H, and L, on the basis of (4S,6S)-6-benzyloxymethyl-4-methyltetrahydro-2H-pyran-2-one prepared through cyclopropanol intermediates.

机译：基于（4S，6S）-，已开发出一种新的简单有效的方法，用于细胞毒性大内酯，两性霉素B，D，G，H和L的C-7-C-14结构单元的不对称合成。通过环丙醇中间体制得6-苄氧基甲基-4-甲基四氢-2H-吡喃-2-酮。

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《Russian Journal of Organic Chemistry》 |2015年第7期|共11页
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Mineeva I. V.;
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1. Synthesis of ethyl (2E,5S)-7-{[tert-butyl(dimethyl)silyloxy]-methyl}-5-methylocta-2,7-dienoate, a universal C-7-C-14 building block for the preparation of amphidinolides B, D, G, H, and L [J] . Mineeva I. V. Russian Journal of Organic Chemistry . 2015,第7期

机译：乙基（2E，5S）-7-{[叔丁基（二甲基）甲硅烷基氧基]-甲基} -5-甲基辛基-2,7-二烯酸酯的合成，这是一种通用的C-7-C-14制备方法两性霉素B，D，G，H和L
2. Cyclopropyl Building Blocks for Organic Synthesis,139.Ethyl Cyclopropylidenepyruvate as a Novel Multifunctional Cyclopropyl Building Block: Facile Preparation and Basic Reaction Patterns [J] . Viktor Bagutski, Armin de Meijere Advanced synthesis & catalysis . 2007,第7期

机译：139.有机合成的环丙基砌块139.作为新型多功能环丙基砌块的环丙基亚丙基丙酮酸酯：简便的制备方法和基本的反应模式
3. NEW AND EFFICIENT SYNTHESIS OF EPSILON-4-DIETHOXYPHOSPHONYL-2-METHYL-2-BUTENAL AND OF ETHYL EPSILON-4-DIETHOXYPHOSPHONYL-2-METHYL-2-BUTENOATE, IMPORTANT BUILDING BLOCKS IN RETINOID CHEMISTRY [J] . Albadri H., Collignon N., Aboutjaudet E. Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 1995,第3期

机译：维甲酸化学中重要的结构单元-高效合成ε-四乙二氧代膦酰基-2-甲基-2-丁烯醛和乙基ε-4-二氧代膦酰基-2-甲基-2-丁烯酸酯
4. SYNTHESIS OF ENANTIOPURE DI(TERT-BUTYL) (2S,4S)-4-HYDROXY-6-OXO-1,2-PIPERIDINEDICARBOXYLATE. A USEFUL BUILDING BLOCK FOR THE PREPARATION OF 4-HYDROXYPIPECOLATE DERIVATIVES [O] . 2008

机译：对映异常二（叔丁基）（2S，4S）-4-羟基-6-氧代1,2-哌啶二羧酸甲酯的合成。用于制备4-羟基丙烯酸衍生物的有用构建块

Synthesis of ethyl (2E,5S)-7-{[tert-butyl(dimethyl)silyloxy]-methyl}-5-methylocta-2,7-dienoate, a universal C-7-C-14 building block for the preparation of amphidinolides B, D, G, H, and L

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