Interconversion among mu-silylene, mu-silyl, and mu-silane diruthenium complexes in the presence of dihydrosilane

Hashimoto H.; Hayashi Y.; Aratani I.; Kabuto C.; Kira M.

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Interconversion among mu-silylene, mu-silyl, and mu-silane diruthenium complexes in the presence of dihydrosilane

机译：在存在二氢硅烷的情况下，间甲硅烷基，间甲硅烷基和间硅烷二钌配合物之间的相互转化

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Irradiation of a toluene solution of[Ru-2(CO)(6)-(mu-dppm)(mu-SiTol(2))] (1) in the presence of an excess of Tol(2)SiH(2) produced a Ai-silyl complex, [Ru-2(CO)(5)(SiTol(2)H)-(mu-dppm)(mu-eta(2)-HSiTol(2))] (2), which was further converted to alpha mu-silane complex, [(Ru(CO)(2)(SiTol(2)H))(2)(mu-dppm)(mu-eta(2):eta(2)-H(2)SiTol(2))] (3), quantitatively. Complex 3 released Tol(2)SiH(2) in the presence of CO to regenerate 2, which finally reverted to 1 under thermal conditions. The X-ray crystal structures of 1 and 3 were determined. [References: 37]

机译：在过量的Tol（2）SiH（2）存在下辐照[Ru-2（CO）（6）-（mu-dppm）（mu-SiTol（2））]（1）的甲苯溶液ai-甲硅烷基络合物，[Ru-2（CO）（5）（SiTol（2）H）-（mu-dppm）（mu-eta（2）-HSiTol（2））]（2）转换为αmu-硅烷络合物，[[Ru（CO）（2）（SiTol（2）H））（2）（mu-dppm）（mu-eta（2）：eta（2）-H（2） SiTol（2））]（3）进行定量分析。配合物3在CO存在下释放Tol（2）SiH（2）来再生2，最终在热条件下恢复为1。确定了1和3的X射线晶体结构。 [参考：37]

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《Organometallics》 |2002年第8期|共3页
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Hashimoto H.; Hayashi Y.; Aratani I.; Kabuto C.; Kira M.;
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中图分类有机化学;有机质材料;
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1. Interconversion among mu-silylene, mu-silyl, and mu-silane diruthenium complexes in the presence of dihydrosilane [J] . Hashimoto H., Hayashi Y., Aratani I., Organometallics . 2002,第8期

机译：在存在二氢硅烷的情况下，间甲硅烷基，间甲硅烷基和间硅烷二钌配合物之间的相互转化
2. Bis(mu-silylene)-Bridged Dinuclear Rhodium(O) Complex and Its Palladium(O) and Platinum(O) Analogues.Theoretical Study of Their Electronic Structure,Bonding Nature,and Interconversion between mu/-Disilene-Bridged Form and Bis(mu-silylene)-Bridged [J] . Singo Nakajima, Yoshihide Nakao, Hirofumi Sato Organometallics . 2004,第20期

机译：双（间亚甲硅烷基）桥连的双核铑（O）配合物及其钯（O）和铂（O）的类似物。它们的电子结构，键合性质以及mu / -Disilene桥接形式与Bis（）之间的相互转换的理论研究间亚甲硅烷基）-桥连
3. Stoichiometric hydrosilylation of nitriles and catalytic hydrosilylation of imines and ketones using a mu-silane diruthenium complex [J] . Hashimoto H., Aratani I., Kabuto C., Organometallics . 2003,第11期

机译：使用mu-硅烷二钌络合物的腈的化学计量氢化硅烷化和亚胺和酮的催化氢化硅烷化
4. Synthesis and Reactivity of Diphosphine-Bridged Diruthenium Complexes [C] . Yoshihiro Miyake, Yohei Nomaguchi, Masahiro Yuki Symposium on Organometallic Chemistry . 2007

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5. Theoretical studies on intermolecular versus intramolecular carbon-hydrogen bond activation in rhodium, iridium, and zirconium complexes, and on the ethene to hydridovinyl interconversion in rhodium and iridium complexes [D] . Jimenez-Catano, Rogelio. 1995

机译：铑，铱和锆络合物中分子间和分子内碳氢键活化的理论研究，以及铑和铱络合物中乙烯向氢化乙烯基的相互转化的理论研究
6. Thermo- and light-triggered reversible interconversion of dysprosium–anthracene complexes and their responsive optical magnetic and dielectric properties [O] . Xin-Da Huang, Ge-Hua Wen, Song-Song Bao, 2021

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7. Structures and Reactivities of Diruthenium Dithiolene Complexes and Triruthenium Sulfido Clusters Derived from a Hydrosulfido-Bridged Diruthenium Complex. [O] . Shigeki Kuwata, Masahiro Andou, Kohjiro Hashizume, 1998

机译：甲状腺二硫代乙烯配合物的结构和反应性和衍生自氢磺酰桥甲醛络合物的三磺酰磺酰簇。
8. Chemistry of Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 90. (1) Synthesis of the Complexes (W2M2(mu-CO)(mu-CMe)(mu3-CMe)-(Mu-PPh2)2(CO)3(eta-C5H5)2) (M = Rh or Ir) and Related Tetra- and Penta-nuclear Metal Compounds: Interconversion of Ketenyl and Lambda(5) -Phospha-alkyne Ligands Bridging Tungsten-Rhodium Bonds. [R] . Davies, S. J., Stone, F. G. 1989

机译：具有桥接卡宾或卡宾配体的多核金属配合物的化学。部分90.（1）配合物的合成（W2m2（mu-CO）（mu-Cme）（mu3-Cme） - （mu-pph2）2（CO）3（eta-C5H5）2）（m = Rh或Ir）和相关的四核和五核金属化合物：Ketenyl和Lambda（5）-phospha-alkyne配体桥联钨 - 铑键的相互转化。

Interconversion among mu-silylene, mu-silyl, and mu-silane diruthenium complexes in the presence of dihydrosilane

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