IODINATION OF (E)-2,2,5,5-TETRAMETHYL-3,4-DIPHENYLHEX-3-ENE - CATALYTIC EFFECTS OF SILVER TRIFLATE AND WATER IN THE I-2/AG2SO4 IODINATION

Sekher P.; Luzik ED.; Gano JE.

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IODINATION OF (E)-2,2,5,5-TETRAMETHYL-3,4-DIPHENYLHEX-3-ENE - CATALYTIC EFFECTS OF SILVER TRIFLATE AND WATER IN THE I-2/AG2SO4 IODINATION

机译：（E）-2,2,2,5,5-叔甲基-3,4-二苯基己基-3-烯的碘化-I-2 / AG2SO4碘化中银和水的催化作用

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(E)-2,2,5,5-Tetramethyl-3,4-diphenylhex-3-ene does not iodinate under normal conditions. Silver trifluoromethanesulfonate catalysis of the silver sulfate/iodine promoted reaction is shown to add versatility to this reation and successfully produce (E)-3-(4'-iodophenyl)-2,2,5,5-tetramethyl-4-phenylhex-3-ene and (E)-2,2,5,5-tetramethyl-3,4-di(4'-iodophenyl)hex-3-ene in good yield under mild conditions. Success is shown to be dependent upon the presence of a trace of water in the dichloromethane solvent. [References: 11]

机译：（E）-2,2,5,5-四甲基-3,4-二苯基己基-3-烯在正常条件下不碘化。三氟甲磺酸银催化的硫酸银/碘促进的反应显示出增加了该反应的多功能性，并成功生产了（E）-3-（4'-碘苯基）-2,2,5,5-四甲基-4-苯基己三-烯和（E）-2,2,5,5-四甲基-3,4-二（4'-碘苯基）己-3-烯在温和条件下的收率很高。成功与否取决于二氯甲烷溶剂中是否存在微量水。 [参考：11]

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来源
《Synthetic Communications》 |1997年第20期|共6页
作者
Sekher P.; Luzik ED.; Gano JE.;
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正文语种 eng
中图分类有机化学;
关键词
Sulfate; Iodine;

机译：硫酸盐;碘;

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1. IODINATION OF (E)-2,2,5,5-TETRAMETHYL-3,4-DIPHENYLHEX-3-ENE - CATALYTIC EFFECTS OF SILVER TRIFLATE AND WATER IN THE I-2/AG2SO4 IODINATION [J] . Sekher P., Luzik ED., Gano JE. Synthetic Communications . 1997,第20期

机译：（E）-2,2,2,5,5-叔甲基-3,4-二苯基己基-3-烯的碘化-I-2 / AG2SO4碘化中银和水的催化作用
2. A Direct iondination method with iodine and silver triflate for the synthesis of spect and pet imaging agent precursors [J] . G.Keith Mulholland, Qi-Huang Zheng Synthetic Communications . 2001,第20期

机译：碘和三氟甲磺酸银的直接电离方法用于合成斑点和宠物显像剂前体
3. Mixed-valence, disordered structures and characterization of iodine-doped phthalocyanines: [YbPc2]I-2 and [(AsPc)(Pc)]I-2 [J] . Janczak J., Jezierski A., Kubiak R. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1999,第9期

机译：碘掺杂酞菁的混合价，无序结构和表征：[YbPc2] I-2和[（AsPc）（Pc）] I-2
4. Theoretical evaluation of iodine and selenium speciation in the natural waters of iodine-deficient territories [C] . Liudmila Kolmykova, Elena Korobova, Boris Ryzhenko, International Symposium on Water-Rock Interaction . 2019

机译：碘缺乏地区天然水域碘和硒形态的理论评价
5. Base-Promoted Stoichiometric Alkyl Carbon-Halogen Bond Cleavage and Catalytic Hydrodehalogenation with Water by Rhodium Porphyrins and Iodine-Catalyzed Carbon-Carbon σ-Bond Hydrogenation with Water [D] . Yang, Wu. 2018

机译：通过铑卟啉和碘催化的碳 - 碳Σ - 致水与水的水基促进化学计量烷基卤素碳 - 卤素粘膜和催化力加氢钠
6. Correlations of water iodine concentration to earlier goitre frequency in Sweden—an iodine sufficient country with long-term iodination of table salt [O] . Sofia Manousou, Maja Stål, Robert Eggertsen, 2019

机译：瑞典的碘水含量与早期甲状腺肿频率的相关性-一个碘充足的国家长期食用食盐加碘
7. A REVISION OF THE ATOMIC WEIGHTS OF SILVER AND IODINE. SECOND PAPER. THE RATIO OF SILVER TO IODINE. [O] . Gregory Paul Baxter 1910

机译：修改银和碘的原子重量。第二张纸。银与碘的比例。

IODINATION OF (E)-2,2,5,5-TETRAMETHYL-3,4-DIPHENYLHEX-3-ENE - CATALYTIC EFFECTS OF SILVER TRIFLATE AND WATER IN THE I-2/AG2SO4 IODINATION

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