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Mechanical and Microstructure Characterization of High Aspect Ratio Electroplated Through-Wafer Copper Interconnects

机译:高纵横比电镀通晶铜互连的机械和微观结构表征

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In this paper, we present the mechanical characterization of high aspect ratio through-wafer electroplated copper interconnects. Copper was deposited in very high aspect ratio (~15) and narrow DRIE etched through-vias (15 μm) in silicon substrate by a special electrodeposition technique. Since the basic understanding of the mechanical and material properties of electroplated copper is very critical for the development of next generation electronic devices and 3-D wafer level packaging, these properties and the grain structure of electroplated copper were measured by appropriate characterization techniques. The elastic modulus and the hardness of electroplated copper were measured by nanoindentation continuous stiffness measurement, while the grain structure of electroplated copper was found out by atomic force microscope. The induced strain, a result of mismatch in coefficient of thermal expansion, was studied by digital image speckle correlation analysis, when the copper interconnects were subjected to a temperature cycle from 25°C to 125°C. The Young's modulus and the hardness of electroplated copper interconnects measured at the top of interconnects (150 GPa and, 2.4 GPa, respectively) were found to be higher than the measured values at the cross-section of copper pillars (136 GPa and, 2.0 GPa respectively). It was found that the indentation modulus along the {111} plain is about 10-25% more than that along {100}. As a result of this difference, the copper pillars form texture and have preferred crystal orientation along the z-axis.
机译:在本文中,我们介绍了通过晶片电镀铜互连的高纵横比的力学表征。通过特殊的电沉积技术在非常高的纵横比(〜15)和硅衬底中的窄DRIE蚀刻通过通孔(15μm)沉积铜。由于对电镀铜的机械和材料性能的基本理解对于下一代电子器件和3-D晶片水平封装的开发非常关键,因此通过适当的表征技术测量电镀铜的这些性质和晶粒结构。通过纳米凸缘连续刚度测量测量电镀铜的弹性模量和硬度,而通过原子力显微镜发现电镀铜的晶粒结构。通过数字图像散斑相关分析研究了热膨胀系数中的诱导应变,当铜互连从25℃至125℃进行温度循环时,研究了热膨胀系数。发现杨氏模量和在互连顶部测量的电镀铜互连的硬度(分别为150GPa和2.4GPa)高于铜柱横截面的测量值(136GPa,2.0GPa分别)。发现沿{111}平原的缩进模量比{100}更高约10-25%。由于这种差异,铜柱形成纹理并沿Z轴具有优选的晶体取向。

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