Chelating dialkoxide titanium complex: A versatile building block for the construction of heterometallic derivatives

Fandos R; Hernandez C; Otero A; Pastor C; Terreros P; Aullon G; Alvarez S

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Chelating dialkoxide titanium complex: A versatile building block for the construction of heterometallic derivatives

机译：螯合的二氧化钛钛配合物：用于构建杂金属衍生物的多功能构建基块

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The heterometallic complex [TiCp*(O(2)Bz)(2)AlMe2] (2) has been synthesised by reaction of [TiCp*(O(2)Bz)(OBzOH)] (1) with A]Me, (Cp*=eta(5)-C5Me5; Bz=benzyl). Complex 1 reacts with HOTf to yield the cationic derivative [TiCp*-(OBzOH)(2)]OTf (3) (HOTf=HSO3CF3). Compound 3 reacts with [{M(mu-OH)(cod)}(2)] (M = Rh, Ir; cod = cyclooctadiene) to render the early-late heterometallic complexes [TiCp*(O(2)Bz)(2)(M(cod)}(2)]OTf (M=Rh (4); Ir (5)). The molecular structure of complex 4 has been established by single-crystal X-ray diffraction studies.

机译：杂金属配合物[TiCp *（O（2）Bz）（2）AlMe2]（2）是通过[TiCp *（O（2）Bz）（OBzOH）]（1）与A] Me反应合成的，（ Cp * ＝ eta（5）-C5Me5; Bz ＝苄基）。配合物1与HOTf反应以产生阳离子衍生物[TiCp *-（OBzOH）（2）] OTf（3）（HOTf ＝ HSO3CF3）。化合物3与[{M（mu-OH）（cod）}（2）]反应（M = Rh，Ir; cod =环辛二烯）产生早期的杂金属配合物[TiCp *（O（2）Bz）（ 2）（M（cod）}（2）] OTf（M = Rh（4）; Ir（5））。配合物4的分子结构已通过单晶X射线衍射研究确定。

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《Chemistry: A European journal》 |2007年第10期|共6页
作者
Fandos R; Hernandez C; Otero A; Pastor C; Terreros P; Aullon G; Alvarez S;
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正文语种 eng
中图分类化学;
关键词
density functional calculations; heterometallic complexes; rhodium; titanium; BRIDGED BIS(PHENOLATO) LIGAND; HYDROXIDE COMPLEXES; MOLECULAR-STRUCTURE; REACTIVITY; POLYMERIZATION; CHEMISTRY; CATALYSTS; TITANATRANES; ZIRCONIUM; CP(ASTERISK)=ETA(5)-C(5)ME(5);

机译：密度泛函计算;杂金属配合物;铑;钛;桥联BIS（苯酚）配体;氢氧化物络合物;分子结构;反应性;聚合;化学;化学性质;催化剂;钛烷;锆;CP（ASTERISK）5 ）ME（5）;

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1. Chelating dialkoxide titanium complex: A versatile building block for the construction of heterometallic derivatives [J] . Fandos R, Hernandez C, Otero A, Chemistry: A European journal . 2007,第10期

机译：螯合的二氧化钛钛配合物：用于构建杂金属衍生物的多功能构建基块
2. Syntheses, structures, and magnetic properties of low-dimensional heterometallic complexes based on the versatile building block [(Tp)Cr(CN) _3]~- [J] . Yao M.-X., Wei Z.-Y., Gu Z.-G., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2011,第17期

机译：基于通用结构单元[（Tp）Cr（CN）_3]〜-的低维杂金属配合物的合成，结构和磁性
3. Rational synthesis and magnetic properties of a family of low-dimensional heterometallic Cr-Mn complexes based on the versatile building block [Cr(2,2 '-bipyridine)(CN)(4)](-) [J] . Zhang YZ, Gao S, Wang ZM, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2005,第13期

机译：基于通用结构单元[Cr（2,2'-联吡啶）（CN）（4）]（-）的低维杂金属Cr-Mn配合物族的合理合成和磁性能
4. Alkynes as Versatile Building Blocks for the Construction of Small Molecules [C] . Mauro Marcolini, Roberto Cipolletti, Giustino Di Antonio European Symposium on Organic Chemistry . 2009

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机译：吩嗪：多核和杂金属配合物的结构单元，其中配体充当电子受体和自由基抽象剂。
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7. Rational Synthesis and Magnetic Properties of a Family of Low-Dimensional Heterometallic Cr-Mn Complexes Based on the Versatile Building Block Cr(2, 2-bpy)(CN)4- [O] . -1

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Chelating dialkoxide titanium complex: A versatile building block for the construction of heterometallic derivatives

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