Carbon-carbon bond formation via palladium catalyzed reactions of organomercurials with acylhalides

P.G.More; N.V.Dalave; (Mrs.) A.S.Lawand

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Carbon-carbon bond formation via palladium catalyzed reactions of organomercurials with acylhalides

机译：通过有机汞与酰基卤的钯催化反应形成碳-碳键

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The palladium catalyzed acyldemetallation reactions of methyl mercury iodide provide a mild,selective and general method for the construction of new C-C bond i.e.for the synthesis of unsymmetrical ketone.The reaction proceeds in acetone,in the presence of a nucleophilic catalyst (iodide ion),at room temperature.The catalytic cycle involved in the reaction consists of a sequence of oxidative addition,transmetallation and reductive elimination steps.The role played by the iodide ion as a nucleophilic catalyst is discussed.

机译：甲基碘甲烷的钯催化的酰基脱金属反应为构建新的CC键（即合成不对称酮）提供了温和，选择性和通用的方法。该反应在丙酮中，亲核催化剂（碘离子）存在下进行，反应中涉及的催化循环由一系列的氧化加成，金属间转移和还原消除步骤组成。讨论了碘离子作为亲核催化剂的作用。

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《Journal of the Indian Chemical Society》 |2007年第4期|共2页
作者
P.G.More; N.V.Dalave; (Mrs.) A.S.Lawand;
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正文语种 eng
中图分类化学;
关键词
Palladium catalysis; acyldemetallation reactions; organomercurials.;

机译：钯催化;酰基脱金属反应;有机缩醛;

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1. Carbon-carbon bond formation via palladium catalyzed reactions of organomercurials with acylhalides [J] . P.G.More, N.V.Dalave, (Mrs.) A.S.Lawand Journal of the Indian Chemical Society . 2007,第4期

机译：通过有机汞与酰基卤的钯催化反应形成碳-碳键
2. Palladium-assisted formation of carbon-carbon bonds. Part 10. Insertion reactions of isocyanides into the Pd-C bond of orthopalladated primary amines. Synthesis of 2-R-aminoisoindolinium salts (R = Bu-t, 2,6-xylyl) [J] . Vicente J., Saura-Llamas I., Grunwald C., Organometallics . 2002,第17期

机译：钯辅助的碳-碳键形成。第10部分。异氰酸酯插入原钯的伯胺的Pd-C键中的插入反应。 2-R-氨基异吲哚鎓盐的合成（R = Bu-t，2,6-二甲苯基）
3. Alkynyl-B(dan)s in Various Palladium-Catalyzed Carbon-Carbon Bond-Forming Reactions Leading to Internal Alkynes, 1,4-Enynes, Ynones, and Multiply Substituted Alkenes [J] . Tani Tomohiro, Sawatsugawa Yuuki, Sano Yusuke, Advanced synthesis & catalysis . 2019,第8期

机译：炔基-B（DAN）在各种钯催化的碳 - 碳键形成反应中，形成内部炔烃，1,4- inynes，ynones和乘法取代的烯烃
4. Catalytic Carbon-Carbon Bond Formation Reactions with Bis(oxazolinyl)phenyl-palladium(Phebox-Pd)Catalysts [C] . Seiji Iwasa, Toshihide Takemoto, Daisuke Murata, Symposium on Organometallic Chemistry . 2003

机译：催化碳 - 碳键形成反应双（恶唑啉基）苯基 - 钯（Phebox-Pd）催化剂
5. Exploration of alpha-Diazocarbonyl Compounds for Transition-Metal Catalyzed Carbon-Carbon Bond Formations. Development of Palladium-Catalyzed Stereoselective Synthesis of Trisubstituted Alkenes and the Synthesis of Quaternary alpha,alpha-Heterodiaryl Carboxylic Acids by Rhodium-Catalyzed Multi-Component Coupling Reactions. [D] . Tsoi, Yuk Tai. 2012

机译：探索用于过渡金属催化的碳-碳键形成的α-重氮羰基化合物。铑催化的多组分偶合反应在钯催化的立体选择性合成三取代的烯烃上的发展和季铵的α，α-杂二芳基羧酸的合成。
6. Recoverable Palladium-Catalyzed Carbon-Carbon Bond Forming Reactions under Thermomorphic Mode: Stille and Suzuki-Miyaura Reactions [O] . Eskedar Tessema, Vijayanath Elakkat, Chiao-Fan Chiu, 2021

机译：在热形模式下可恢复的钯催化的碳 - 碳键形成反应：stille和suzuki-miyaura反应
7. On the mechanism of formation of homocoupled products in the carbon-carbon crosscoupling reaction catalyzed by palladium complexes containing rigid bidentate nitrogen ligands: evidence for the exchange of organic groups between palladium and the transmet [O] . van Asselt, R., Elsevier, C.J. 1994

机译：含刚性双齿氮配体的钯配合物催化的碳-碳交叉偶联反应中均相产物形成机理的研究：钯与互感剂之间有机基团交换的证据

Carbon-carbon bond formation via palladium catalyzed reactions of organomercurials with acylhalides

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