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Electrical and structural properties of antimony-doped p-type ZnO nanorods with self-corrugated surfaces

机译:具有自波纹表面的掺锑p型ZnO纳米棒的电学和结构性能

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We report on p-type conductivity in antimony (Sb)-doped ZnO (ZnO:Sb) nanorods which have self-corrugated surfaces. The p-ZnO:Sb-ZnO nanorod diode shows good rectification characteristics, confirming that a p-n homojunction is formed in the ZnO nanorod diode. The low-temperature photoluminescence (PL) spectra of the ZnO:Sb nanorods reveal that the p-type conductivity in p-ZnO:Sb is related to the SbZn-2V Zn complex acceptors. Transmission electron microscopy (TEM) analysis of the ZnO:Sb nanorods also shows that the p-type conductivity is attributed to the SbZn-2V Zn complex acceptors which can be easily formed near the self-corrugated surface regions of ZnO:Sb nanorods. These results suggest that the SbZn-2VZn complex acceptors are mainly responsible for the p-type conductivity in ZnO:Sb nanorods which have corrugated surfaces.
机译:我们报告了具有自波纹表面的锑(Sb)掺杂的ZnO(ZnO:Sb)纳米棒中的p型电导率。 p-ZnO:Sb / n-ZnO纳米棒二极管显示出良好的整流特性,证实在ZnO纳米棒二极管中形成了p-n同质结。 ZnO:Sb纳米棒的低温光致发光(PL)光谱表明,p-ZnO:Sb中的p型电导率与SbZn-2V Zn络合物受体有关。 ZnO:Sb纳米棒的透射电子显微镜(TEM)分析还表明,p型导电性归因于SbZn-2V Zn络合物受体,该受体很容易在ZnO:Sb纳米棒的自波纹表面区域附近形成。这些结果表明,SbZn-2VZn络合物受体主要负责具有波纹表面的ZnO:Sb纳米棒中的p型导电性。

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