Metal complexes of 2,6-bis[(pyrazol-1-yl)methyllpyridine: The search for aryl-pyrazolyl embrace interactions as a synthon for crystal engineering

Reger DL; Semeniuc RF; Smith MD

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Metal complexes of 2,6-bis[(pyrazol-1-yl)methyllpyridine: The search for aryl-pyrazolyl embrace interactions as a synthon for crystal engineering

机译：2,6-双[（吡唑-1-基）甲基哌啶的金属配合物：寻求芳基-吡唑基拥抱相互作用作为晶体工程的合成子

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The 2,6-py(CH2-pz)(2) ligand was used to prepare metal complexes as follows: [py(CH(2)pz)(2)](BiI3), {Ag[py(CH(2)pz)(2)](OTf)&BULL; CH3CN}(&INFIN;), {PtCl[py(CH(2)pz)(2)](2)}(BF4), {Cd[py(CH(2)pz)(2)](2)}(BF4)(2)&BULL;[4,4'-bipyl-0.5H(2)O, and {Cd[phen](3)}(2)(BF4)(4)&BULL;[py(CH(2)pz)(2)]&BULL; 5H(2)O (py = pyridyl, pz = pyrazolyl, and phen = 1,10-phenanthroline). The solid state structures of each complex show that all five compounds are organized by noncovalent forces into complex extended structures. Each structure has a common supramolecular organizational feature between the ligands of a cooperative offset face-to-face π-π stacking and C-H&BULL;&BULL;&BULL;π interaction formed from both the pyridyl and the pyrazolyl rings that is termed the aryl-pyrazolyl embrace. The systematic analysis of this synthon showed that the π-π stacking component of the aryl-pyrazolyl embrace always involves rings of the same type.

机译：2,6-py（CH2-pz）（2）配体用于制备金属配合物，如下所示：[py（CH（2）pz）（2）]（BiI3），{Ag [py（CH（2） pz）（2）]（OTf）＆BULL; CH3CN}（＆INFIN;），{PtCl [py（CH（2）pz）（2）]（2）}（BF4），{Cd [py（CH（2）pz）（2）]（2）}（ BF4）（2）＆BULL; [4,4'-bipyl-0.5H（2）O和{Cd [phen]（3）}（2）（BF4）（4）＆BULL; [py（CH（2） pz）（2）]＆BULL; 5H（2）O（py =吡啶基，pz =吡唑基，和phen = 1,10-菲咯啉）。每个复合物的固态结构表明，所有五种化合物都是通过非共价力组织成复杂的延伸结构。每个结构在合作的错位面对面π-π堆积和由吡啶基和吡唑基环形成的C-H＆BULL;＆BULL;＆BULL;π相互作用的配体之间都有一个共同的超分子组织特征，这种相互作用被称为芳基-吡唑基拥抱。对该合成子的系统分析表明，芳基-吡唑基环抱的π-π堆积成分始终涉及相同类型的环。

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《Crystal growth & design》 |2005年第3期|共10页
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Reger DL; Semeniuc RF; Smith MD;
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正文语种 eng
中图分类晶体学;
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HYDROGEN-BONDED NETWORKS; BIDENTATE BASE SYSTEMS; COPPER(II) COMPLEXES; INTERMOLECULAR INTERACTIONS; COORDINATION POLYMERS; SILVER(I) COMPLEXES; PHENYL INTERACTIONS; TRIDENTATE LIGANDS; MOTIFS; DESIGN;

机译：氢键网络;二价基体系;铜（II）络合物;分子间相互作用;配位聚合物;银（I）络合物;苯酚相互作用;三齿配体;MOTIFS;设计;

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1. Metal complexes of 2,6-bis[(pyrazol-1-yl)methyllpyridine: The search for aryl-pyrazolyl embrace interactions as a synthon for crystal engineering [J] . Reger DL, Semeniuc RF, Smith MD Crystal growth & design . 2005,第3期

机译：2,6-双[（吡唑-1-基）甲基哌啶的金属配合物：寻求芳基-吡唑基拥抱相互作用作为晶体工程的合成子
2. #pi#-#pi# interactions in organometallic systems.Crystalstructures and spectroscopic properties of luminescent Mono-,Bi-,and trinuclear trans-cyclometalated platinum(II) complexes derived from 2,6-diphenylpyridine [J] . Wei Lu, Michael C.W.Chan, Kung-Kai Cheung, Organometallics . 2001,第12期

机译：有机金属体系中的#pi＃-＃pi＃相互作用.2,6-二苯基吡啶衍生的发光单，双和三核反式环金属化铂（II）配合物的晶体结构和光谱性质
3. pi-pi interactions in organometallic systems. Crystal structures and spectroscopic properties of luminescent mono-, bi-, and trinuclear trans-cyclometalated platinum(II) complexes derived from 2,6-diphenylpyridine [J] . Lu W., Cheung KK., Che CM., Organometallics . 2001,第12期

机译：有机金属系统中的pi-pi相互作用。衍生自2,6-二苯基吡啶的单核，双核和三核反式环金属化铂（II）配合物的晶体结构和光谱性质
4. The Preparation of Metallosupramolecular Polymers and Gels by Utilizing 2,6-bis-(1'-Methyl-benzimidazolyl)Pyridine-Metal Ion Interactions [C] . J. Benjamin Beck, Stuart J. Rowan Symposium on Metal-containing and metallosupramolecular polymers and materials . 2006

机译：利用2,6-双（1'-甲基 - 苯并咪唑基）吡啶 - 金属离子相互作用，制备金属粥分子聚合物和凝胶
5. 1. ortho-linked polyaryloxide and sterically hindered biphenoxide ligands: Synthesis and metal coordination chemistry. 2. Synthesis, characterization, and reactivity of bis[hydrotris(pyrazol-1-yl)borato]titanium(II). [D] . Kayal, Ajay. 2002

机译：1.邻位连接的聚芳氧基化物和位阻联苯氧基化物配体：合成和金属配位化学。 2.双[氢三（吡唑-1-基）硼酸]钛（II）的合成，表征和反应性。
6. Crystal structure of bis{(35-dimethylpyrazol-1-yl)dihydro3-(pyridin-2-yl)pyrazol-1-ylborato}iron(II) [O] . Sascha Ossinger, Christian Näther, Felix Tuczek 2020

机译：双{（35-二甲基吡唑-1-基）的晶体结构二氢3-（吡啶-2-基）吡唑-1-基铁（II）
7. The copper(II) complexes di-mu-bromo-bis{[2,6-bis(pyrazol-1-yl)pyridine]perchloratocopper(II)} and [2,6-bis(pyrazol-1-yl)pyridine]dibromocopper(II). [O] . Chakrabarty, S, Poddar, RK, Poulsen, RD, 2004

机译：铜（II）络合物二-溴-双{[2,6-双（吡唑-1-基）吡啶]高氯铜（II）}和[2,6-双（吡唑-1-基）吡啶]二溴铜（II）。
8. Chemistry of Polynuclear Metal Complexes with Bridging Carbene or Carbyne Ligands. Part 84. Carbarorane Tungsten Platinum Complexes having a MU-CC6H3ME(2)-2,6 Ligand: Crystal Structures of (WPt(MU- CC6H3ME(2)-2,6))(CO)N-(Pet3)(MU- [R] . Devore, D. D., Howard, J. A., Jeffery, J. C., 1989

机译：具有桥接卡宾或卡宾配体的多核金属配合物的化学。部分84.具有mU-CC6H3mE（2）-2,6配体的碳硼烷钨铂配合物：（Wpt（mU-CC6H3mE（2）-2,6））（CO）N-（pet3）（mU-）的晶体结构

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Metal complexes of 2,6-bis[(pyrazol-1-yl)methyllpyridine: The search for aryl-pyrazolyl embrace interactions as a synthon for crystal engineering

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