Crystal structures of nitrato-4-bromo-2-[(2hydroxyethylimino)methyl] phenolatoimidazolecopper and nitrato-4-chloro-2-[(2hydroxyethylimino)methyl] phenolatoimidazolecopper

Chumakov Yu.M.; Tsapkov V.I.; Antosyak B.Ya.; Popovschi L.G.; Bocelli G.; Guly A.P.; Palomares-Sanchez S.A.

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Crystal structures of nitrato-4-bromo-2-[(2hydroxyethylimino)methyl] phenolatoimidazolecopper and nitrato-4-chloro-2-[(2hydroxyethylimino)methyl] phenolatoimidazolecopper

机译：硝基-4-溴-2-[[（2羟乙基亚氨基）甲基]苯酚氨基咪唑铜和硝基4-氯-2-[[（2羟乙基亚氨基）甲基]苯酚氨基咪唑铜的晶体结构

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Nitrato-4-bromo-2-[(2-hydroxyethylimino)methyl]phenolatoimidazolecopper and nitrato-4chloro-2-[(2-hydroxyethylimino)methyl]phenolatoimidazolecopper were synthesized and studied by X-ray diffraction. The crystals are isostructural. The coordination polyhedron of the copper atom can be described as a distorted square pyramid whose basal plane is formed by the phenolic and alcoholic oxygen atoms and the nitrogen atom of the monodeprotonated tridentate azomethine molecule and the imidazole nitrogen atom. The apex of the copper polyhedron is occupied by the oxygen atom of the nitrato group. The complexes are linked together by hydrogen bonds with the participation of the nitrato groups to form a three-dimensional framework.

机译：通过X射线衍射合成并合成了硝基4-溴-2--2-[（2-羟基乙基亚氨基）甲基]苯酚基咪唑铜和硝基-4-氯-2-[（2-羟基乙基亚氨基）甲基]苯酚基咪唑铜。晶体是同构的。铜原子的配位多面体可以描述为扭曲的四棱锥，其底面由酚和醇氧原子和单去质子化三齿偶氮甲碱分子的氮原子和咪唑氮原子形成。铜多面体的顶点被硝基基团的氧原子占据。配合物通过氢键与硝酸根基团的参与连接在一起，形成三维框架。

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《Crystallography reports》 |2012年第2期|共6页
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Chumakov Yu.M.; Tsapkov V.I.; Antosyak B.Ya.; Popovschi L.G.; Bocelli G.; Guly A.P.; Palomares-Sanchez S.A.;
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1. Crystal structures of nitrato-4-bromo-2-[(2hydroxyethylimino)methyl] phenolatoimidazolecopper and nitrato-4-chloro-2-[(2hydroxyethylimino)methyl] phenolatoimidazolecopper [J] . Chumakov Yu.M., Tsapkov V.I., Antosyak B.Ya., Crystallography reports . 2012,第2期

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Crystal structures of nitrato-4-bromo-2-[(2hydroxyethylimino)methyl] phenolatoimidazolecopper and nitrato-4-chloro-2-[(2hydroxyethylimino)methyl] phenolatoimidazolecopper

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