Crystal Structure of the Azido-Bridged Copper(II) Complex [Cu2L2((1,1)-N-3)(2)] Based on the 2-[(3-Amino-2,2-Dimethylpropylimino)-Methyl]-4-Bromophenol Schiff Base Ligand

Ghaemi A.; Keyvani B.; Fayyazi K.; Rudbari H. A.

首页> 外文期刊>Journal of structural chemistry >Crystal Structure of the Azido-Bridged Copper(II) Complex [Cu2L2((1,1)-N-3)(2)] Based on the 2-[(3-Amino-2,2-Dimethylpropylimino)-Methyl]-4-Bromophenol Schiff Base Ligand

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Crystal Structure of the Azido-Bridged Copper(II) Complex [Cu2L2((1,1)-N-3)(2)] Based on the 2-[(3-Amino-2,2-Dimethylpropylimino)-Methyl]-4-Bromophenol Schiff Base Ligand

机译：基于2 - [（3-氨基-2,2-二甲基丙基丙基氨基氨基） - - 4-溴苯酚Schiff Base配体

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New end-on azido-bridged dinuclear copper(II) complex [Cu2L2((1,1)-N-3)(2)] (I) (HL = 2-[(3-amino-2,2-dimethylpropylimino)-methyl]-4-bromophenol) is synthesized and characterized by the elemental analysis and FT-IR spectroscopy. The crystal structure of I is determined by X-ray diffraction. The crystal of I is monoclinic, space group P2(1/c), a = 10.7926(4) angstrom, b = 12.4222(4) angstrom, c = 11.0894(4) angstrom, = 100.085(2)degrees, V = 1463.76(9) angstrom(3), Z = 2. The crystal structure shows that the structure contains [Cu2L2((1,1)-N-3)(2)] units joined together by intermolecular H-bonding interactions to form a 2D rectangular grid.

机译：新的结束αzido桥桥二核铜（II）复合物[Cu 2L 2（（1,1）-N-3）（2）]（1）（HL = 2 - [（3-氨基-2,2-二甲基丙基丙基咪唑酯） - 通过元素分析和FT-IR光谱合成甲基溴苯酚）和特征。 I的晶体结构由X射线衍射确定。 I的晶体是单斜晶，空间组P2（1 / C），A = 10.7926（4）埃，B = 12.4222（4）埃，C = 11.0894（4）埃，= 100.085（2）度，V = 1463.76 （9）埃赫斯特罗姆（3），Z = 2.晶体结构表明，该结构含有通过分子间H键合相互作用连接在一起以形成2D的单元矩形网格。

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来源
《Journal of structural chemistry》 |2018年第5期|共5页
作者
Ghaemi A.; Keyvani B.; Fayyazi K.; Rudbari H. A.;
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作者单位

Islamic Azad Univ Dept Chem Saveh Branch Saveh Iran;

Islamic Azad Univ Dept Chem Saveh Branch Saveh Iran;

Islamic Azad Univ Dept Chem Saveh Branch Saveh Iran;

Univ Isfahan Dept Chem Esfahan Iran;

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正文语种 eng
中图分类结构化学;
关键词
synthesis; Schiff base ligand; copper(II); crystal structure; 2-(3-amino-2; 2-dimethylpropylimino)-methyl-4-bromophenol; azido-bridged; X-ray diffraction analysis;

机译：合成;Schiff碱配体;铜（II）;晶体结构;2 - [（3-氨基-2;2-二甲基丙基咪啶氨基氨基氨基） - 甲基] -4-溴苯酚;氮杂桥;X射线衍射分析;

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1. Crystal Structure of the Azido-Bridged Copper(II) Complex [Cu2L2((1,1)-N-3)(2)] Based on the 2-[(3-Amino-2,2-Dimethylpropylimino)-Methyl]-4-Bromophenol Schiff Base Ligand [J] . Ghaemi A., Keyvani B., Fayyazi K., Journal of structural chemistry . 2018,第5期

机译：基于2 - [（3-氨基-2,2-二甲基丙基丙基氨基氨基） - - 4-溴苯酚Schiff Base配体
2. Syntheses, characterization, superoxide dismutase, antimicrobial, crystal structure and molecular studies of copper (II) and nickel (II) complexes with 2-((E)-(2, 4-dibromophenylimino) methyl)-4-bromophenol as Schiff base ligand [J] . Bharti Sulakshna, Choudhary Mukesh, Mohan Bharti, Journal of Molecular Structure . 2017,第期

机译：合成，表征，超氧化物歧化酶，铜（II）和镍（II）配合物的二氧化铜（II）和镍（II） - （2,4-二溴苯基氨基）甲基）-4-溴苯酚作为席夫碱配体
3. Preparation of Zinc (II) and Cadmium (II) Complexes of the Tetradentate Schiff Base Ligand 2-((E)-(2-(2-(pyridine-2-yl)-ethylthio)ethylimino)methyl)-4-bromophenol (PytBrsalH) [J] . Ali Aminkhani, Ghasem Karimnezhad, Lotf A. Saghatforoush, Molecules . 2008,第4期

机译：四齿席夫碱配体2-（（E）-（2-（2-（吡啶-2-基）-乙硫基）乙基亚氨基）甲基）-4-溴苯酚的锌（II）和镉（II）配合物的制备PytBrsalH）
4. "Bioinspired" Metal Complexes of Macrocyclic N_4~(2-) and Open Chain N_2O_2~(2-) Schiff base Ligands - a Link between Porphyrins and Salicylaldimines [C] . Ernst-G. Jager German-Italian Meeting of Coimbra Group Universities . 2000

机译：“Bioinspired”宏环的金属配合物N_4〜（2-）和开口链N_2O_2〜（2-） Schiff碱配体 - 卟啉和水杨酰亚胺之间的联系
5. Part I: Synthesis and structural characterization of some transition metal complexes derived from Schiff base ligands Part II: Crystallographic studies of pharmacologically active compounds. [D] . Assey, Gervas E. 2010

机译：第一部分：席夫碱配体衍生的某些过渡金属配合物的合成和结构表征第二部分：药理活性化合物的晶体学研究。
6. Preparation of Zinc (II) and Cadmium (II) Complexes of the Tetradentate Schiff Base Ligand 2-((E)-(2-(2-(pyridine-2-yl)-ethylthio)ethylimino)methyl)-4-bromophenol (PytBrsalH) [O] . Lotf A. Saghatforoush, Ali Aminkhani, Sohrab Ershad, 2008

机译：四齿席夫碱配体2-（（E）-（2-（2-（2-吡啶-2-基）-乙硫基）乙基亚氨基）甲基）-4-溴苯酚的锌（II）和镉（II）配合物的制备PytBrsalH）
7. Crystal structure of a tetranuclear CuII complex with an O,N,N′-donor Schiff base ligand: hexa-μ2-acetato-bis(2-{[(2,2,6,6-tetramethylpiperidin-4-yl)imino]methyl}phenolato-κ3O,N,N′)tetracopper(II) [O] . Guohui Huang, Xiaoxuan Liu 2016

机译：具有O，N，N'-供体席夫碱配体的四核CuII配合物的晶体结构：六-μ2-乙酸根 - 双（2 - {[（2,2,6,6-四甲基哌啶-4-基）亚氨基]甲基}苯酚-κ3O，N，N'）tetracopper（II）
8. Novel Square Pyramidal Copper(II) Complexes of the Stereospecific Linear NSNNTetradentate Ligand N-((2-Pyridyl)methyl)-2-((2-Aminoethyl)thio) Acetamide (pygeH). The Crystal Structures of (Cu(pyge)X) (X = Br, N3) [R] . Toscano, P. J., Fordon, K. J., Macherone, D., 1990

机译：新型方形金字塔形铜（II）配合物的立体特异性线性NsNN四齿配体N - （（2-吡啶基）甲基）-2 - （（2-氨基乙基）硫代）乙酰胺（pygeH）。（Cu（pyge）X）（X = Br，N3）的晶体结构

Crystal Structure of the Azido-Bridged Copper(II) Complex [Cu2L2((1,1)-N-3)(2)] Based on the 2-[(3-Amino-2,2-Dimethylpropylimino)-Methyl]-4-Bromophenol Schiff Base Ligand

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