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Coordinate chloride and water-assisted assembly of novel 3D-cageworks of cadmium(II)complex with 4-[N,N-bis(2-cyanoethyl)]aminopyridine

机译:新型配合物4- [N,N-双(2-氰乙基)]氨基吡啶的镉(II)配合物的新型3D笼式氯化物与水的辅助组装

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摘要

Synthesis and structure of the cadmium(II)complex of [Cd~(II)(CEAP)_2(H_2O)(CH_3COO)Cl] {CEAP=4-[N,N-bis(2-cyanoethyl)]amino-pyridine} has been reported.The structure exhibits a novel 3D-cagework assembly with the assistance of the coordinated chloride anion and water molecule via forming multiple hydrogen bonds with the cyanoethyl arms of CEAP.
机译:[Cd〜(II)(CEAP)_2(H_2O)(CH_3COO)Cl] {CEAP = 4- [N,N-双(2-氰基乙基)]氨基吡啶}的镉(II)配合物的合成和结构该结构通过与CEAP的氰乙基臂形成多个氢键,在氯离子和水分子的协同作用下展现出一种新颖的3D笼结构。

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