首页> 外文期刊>Journal of Materials Engineering and Performance >Effect of Si on the Formation and Growth of Intermetallic Compounds at Roll-Bonded Aluminum-Steel (Al-St) Interface
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Effect of Si on the Formation and Growth of Intermetallic Compounds at Roll-Bonded Aluminum-Steel (Al-St) Interface

机译:Si对轧制铝 - 钢(Al-ST)界面在金属间化合物的形成和生长的影响

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摘要

The formation and growth of intermetallic compounds (IMC) were investigated using the Al-St clad materials with additional different Si content to aluminum and steel substrate by differential scanning calorimetry, scanning electron microscopy and energy-dispersive x-ray spectroscopy, x-ray diffraction and transmission electron microscopy. The addition of Si to Al (Al-0.8Si/St) can drastically delay the formation of IMC and accelerate the growth of IMC layer. The Si (Al-0.8Si/St) segregates at the interface and inhibits the diffusion of Al atom to steel before the IMC forms, which further decreases the diffusion depth of Al in the steel layer. By contrast, the addition of Si to St (Al/St-0.8Si) has limited impact on delaying the formation and decelerating the growth of IMC layer. The Si (Al/St-0.8Si) hardly affects the diffusion of Fe atom to the aluminum layer. Among the four clad materials, the major IMC layer (eta-Fe2Al5) always exhibits the parabolic growth phenomenon. The addition of Si cannot influence the phase compositions of IMC at the interface between the eta-Fe2Al5 layer and the aluminum. However, we observe an extra Fe-rich phase beta (1)-Fe3Al at the interface between the Fe2Al5 layer and steel substrate in the Al-0.8Si/St clad material.
机译:通过差示扫描量热法,扫描电子显微镜和能量分散X射线光谱,X射线衍射,使用Al-St Clad材料对铝和钢基板进行另外的不同Si含量的铝和钢基板进行金属间化合物(IMC)的形成和生长。X射线衍射和透射电子显微镜。向Al(Al-0.8Si / ST)加入Si(Al-0.8Si / st)可以急剧延迟IMC的形成并加速IMC层的生长。 Si(Al-0.8Si / ST)在界面处隔离并抑制IMC形式前的Al原子的扩散,这进一步降低了钢层中Al的扩散深度。相比之下,将Si至ST(Al / ST-0.8Si)的加入对延迟形成和减少IMC层的生长影响有限。 Si(Al / ST-0.8Si)几乎不影响Fe原子的扩散到铝层。在四种包层中,主要的IMC层(ETA-FE2AL5)始终表现出抛物线生长现象。在ETA-Fe2Al5层和铝之间的界面中,添加Si不能影响IMC的相组合物。然而,我们在AL-0.8SI / ST层材料中的Fe2Al5层和钢基板之间的界面处观察额外的Fe富含Fe的相β(1)-Fe3al。

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